Polymerization of propylene oxide with a dialkylzinc–hydrazine catalyst
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منابع مشابه
Polymerization of Propylene with [t-BuNSiMe2Ind]TiMe2-MAO Catalyst Systems
ansa-Indenylamidodimethyltitanium complex ([t-BuNSiMe2Ind]TiMe2: 1) was synthesized by one-pot reactions starting from the ligand, MeLi and TiCl4. The structure of 1 was determined by X-ray crystallography and the results obtained revealed that the indenyl ligand coordinate to titanium in an η-tendency. Propylene polymerization was conducted with 1 in toluene or heptane as solvent at 0 ̊C in th...
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Gas phase polymerization of propylene was carried out in a semi-batch minireactor using a commercially supported Ziegler–Natta (ZN) catalyst. The influence of variables including monomer partial pressure, external electron donor, reaction temperature and time on the particle morphology and size distribution was investigated. Generally, more uniform fragmentation and particle densities were obta...
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the interaction of the external donor (propyltrimethoxysilane - ptms) with titanium-magnesium catalysts (tmcs) containing dibutylphthalate (dbp) as internal donor, which were prepared in different ways, was studied by chemical analysis and infrared diffuse reflectance spectroscopy (drifts). the chemical composition of the catalysts after their interaction with heptane solutions of ptms, ptms/al...
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the steps taken in designing a loop reactor for bulk propylene polymerization are discussed. the roles played by several parameters like particle growth factor, catalyst activity and solid fraction on reactor volume at different operating conditions are investigated. at first, based on a fixed production capacity and specific rate of catalyst, reactor volume is determined. next, the length and ...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part A-1: Polymer Chemistry
سال: 1967
ISSN: 0449-296X,1542-9350
DOI: 10.1002/pol.1967.150050417